Award Abstract # 2119688
RII Track-2 FEC: Tri-state Research Institute of Manufacturing for Managing CO2 (TRIMMing CO2)

NSF Org: OIA
OIA-Office of Integrative Activities
Recipient: UNIVERSITY OF LOUISIANA AT LAFAYETTE
Initial Amendment Date: September 16, 2021
Latest Amendment Date: December 11, 2023
Award Number: 2119688
Award Instrument: Cooperative Agreement
Program Manager: Chinonye Nnakwe
cwhitley@nsf.gov
 (703)292-8458
OIA
 OIA-Office of Integrative Activities
O/D
 Office Of The Director
Start Date: October 1, 2021
End Date: September 30, 2025 (Estimated)
Total Intended Award Amount: $6,000,000.00
Total Awarded Amount to Date: $4,500,000.00
Funds Obligated to Date: FY 2021 = $1,500,000.00
FY 2022 = $1,500,000.00

FY 2024 = $1,500,000.00
History of Investigator:
  • Ling Fei (Principal Investigator)
    C00418605@louisiana.edu
  • Shuya Wei (Co-Principal Investigator)
  • Meng Zhou (Co-Principal Investigator)
  • Delia Valles-Rosales (Co-Principal Investigator)
  • David Mebane (Co-Principal Investigator)
  • Xiao-Dong Zhou (Former Principal Investigator)
Recipient Sponsored Research Office: University of Louisiana at Lafayette
104 E UNIVERSITY AVE
LAFAYETTE
LA  US  70503-2014
(337)482-5811
Sponsor Congressional District: 03
Primary Place of Performance: University of Louisiana at Lafayette
131 Rex St
Lafayette
LA  US  70503-2007
Primary Place of Performance
Congressional District:
03
Unique Entity Identifier (UEI): C169K7T4QZ96
Parent UEI: C169K7T4QZ96
NSF Program(s): EPSCoR RII Track-2 FEC,
EPSCoR Research Infrastructure
Primary Program Source: 01002425DB NSF RESEARCH & RELATED ACTIVIT
01002223DB NSF RESEARCH & RELATED ACTIVIT

01002122DB NSF RESEARCH & RELATED ACTIVIT
Program Reference Code(s): 075Z, 7569, 7715, 8037, 8038, 9150, SMET
Program Element Code(s): 194Y00, 721700
Award Agency Code: 4900
Fund Agency Code: 4900
Assistance Listing Number(s): 47.083

ABSTRACT

During the past century, our civilization?s technological advances have been driven by the conversion of carbon-rich fossil fuels into electricity, heat, polymers, fertilizers, and other carbon-based products that are the foundation of modern society. It is now clear that, to avoid catastrophic climate change, we must dramatically and rapidly reduce global emissions of CO2, and additionally remove billions of tons of CO2 from the earth?s atmosphere and oceans by mid-century. The mission of the Tri-state Research Institute of Manufacturing for Managing CO2 (TRIMMing CO2) project is to address the challenge of carbon capture and utilization. The team will develop innovative manufacturing processes and fundamental understanding to advance carbon capture and utilization. The work is enabled by a closely collaborative, well integrated, and highly interdisciplinary network of researchers at the University of Louisiana at Lafayette, New Mexico State University, the University of New Mexico and West Virginia University, as well as the National Energy Technology Laboratory and Idaho National Laboratory. This TRIMMing CO2 project will provide inter-jurisdictional synergistic activities for students, postdocs, and faculty, including exchange of students and faculty, internship at the national labs and industry, and co-advising students while broadening participation in research, with a focus on the engagement of groups currently underrepresented in science.


The expertise of the TRIMMing CO2 team spans the areas of electrochemistry, materials design and characterization, manufacturing, theoretical chemistry, spectroscopy, multi-scale modeling, and machine learning. The planned research activity entails the development of three cutting-edge technologies that will: (i) capture CO2 while producing electricity, (ii) utilize CO2 while storing electric energy, and (iii) convert CO2 to high-value chemicals. The first technical thrust involves the development of molten carbonate fuel cell (MCFC) technology which concentrates CO¬2 while producing electricity. Our research focuses on the use of 3-dimensional electrodes which can improve MCFC performance and stability. The second thrust is the development of a unique energy storage system that utilizes CO2. The third thrust focuses on the conversion of CO2 to high-value chemicals, for instance C2H4 and ethanol. The fourth thrust will assess the quality and economics of component and chemical manufacturing through a ?MAP? program: (i) Modeling of manufacturing and chemical processes, (ii) Artificial intelligence for microstructural image analysis, and (iii) Process integration and techno-economic analysis. The MAP program will provide opportunities for teaming with industry partners on the advisory board for process scale-up. These four thrusts closely integrate technical expertise from four universities and two national labs.

This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

PUBLICATIONS PRODUCED AS A RESULT OF THIS RESEARCH

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(Showing: 1 - 10 of 20)
Dogdibegovic, Emir and Wang, Yudong and Zhou, Xiao-Dong "Origin for electrochemically driven phase transformation in the oxygen electrode for a solid oxide cell" Proceedings of the National Academy of Sciences , v.119 , 2022 https://doi.org/10.1073/pnas.2203256119 Citation Details
Wang, Jianda and Marchetti, Barbara and Zhou, Xiao-Dong and Wei, Shuya "Heterogeneous Electrocatalysts for Metal?CO 2 Batteries and CO 2 Electrolysis" ACS Energy Letters , v.8 , 2023 https://doi.org/10.1021/acsenergylett.2c02445 Citation Details
Fetrow, Christopher James and Carugati, Cameron and Zhou, Xiao-Dong and Wei, Shuya "Electrochemistry of metal-CO2 batteries: Opportunities and challenges" Energy Storage Materials , v.45 , 2022 https://doi.org/10.1016/j.ensm.2021.12.035 Citation Details
Wang, Yudong and Virkar, Anil V. and Khonsari, M. M. and Zhou, Xiao-Dong "Theoretical Analysis of Critical Conditions for Crack Formation and Propagation, and Optimal Operation of SOECs" Journal of The Electrochemical Society , v.169 , 2022 https://doi.org/10.1149/1945-7111/ac5fee Citation Details
Tang, Wei and Ding, Hanping and Bian, Wenjuan and Regalado Vera, Clarita Y. and Gomez, Joshua Y. and Dong, Yanhao and Li, Ju and Wu, Wei and Fan, WeiWei and Zhou, Meng and Gore, Colin and Blackburn, Bryan M. and Luo, Hongmei and Ding, Dong "An Unbalanced Battle in Excellence: Revealing Effect of Ni/Co Occupancy on Water Splitting and Oxygen Reduction Reactions in Triple?Conducting Oxides for Protonic Ceramic Electrochemical Cells" Small , v.18 , 2022 https://doi.org/10.1002/smll.202201953 Citation Details
Thangasamy, Pitchai and He, Rong and Chen, Xinqi and Yu, Kunpeng and Randriamahazaka, Hyacinthe and Chen, Zheng and Luo, Hongmei and Zhou, Xiao?Dong and Zhou, Meng "Organic?Inorganic Hybrid Crystal?Assisted Etching of Nickel Foam for the Collectively Exhaustive Electrochemical Performance of Oxygen Evolution Reaction" Chemistry ? A European Journal , v.29 , 2023 https://doi.org/10.1002/chem.202301469 Citation Details
Thangasamy, Pitchai and He, Rong and Randriamahazaka, Hyacinthe and Chen, Xinqi and Zhang, Yizhi and Luo, Hongmei and Wang, Haiyan and Zhou, Meng "Collectively exhaustive electrochemical hydrogen evolution reaction of polymorphic cobalt selenides derived from organic surfactants modified Co-MOFs" Applied Catalysis B: Environmental , v.325 , 2023 https://doi.org/10.1016/j.apcatb.2023.122367 Citation Details
He, Rong and Sun, Quanwen and Thangasamy, Pitchai and Chen, Xinqi and Zhang, Yizhi and Wang, Haiyan and Luo, Hongmei and Zhou, Xiao-Dong and Zhou, Meng "Accelerate oxygen evolution reaction by adding chemical mediator and utilizing solar energy" International Journal of Hydrogen Energy , v.48 , 2023 https://doi.org/10.1016/j.ijhydene.2022.11.294 Citation Details
He, Rong and Zhou, Larissa and Tenent, Robert and Zhou, Meng "Basics of the scanning electrochemical microscope and its application in the characterization of lithium-ion batteries: a brief review" Materials Chemistry Frontiers , v.7 , 2023 https://doi.org/10.1039/D2QM01079H Citation Details
Bian, Wenjuan and Wu, Wei and Wang, Baoming and Tang, Wei and Zhou, Meng and Jin, Congrui and Ding, Hanping and Fan, Weiwei and Dong, Yanhao and Li, Ju and Ding, Dong "Revitalizing interface in protonic ceramic cells by acid etch" Nature , v.604 , 2022 https://doi.org/10.1038/s41586-022-04457-y Citation Details
Wang, Jianda and Powell, Matthew and Alcala, Ryan and Fetrow, Christopher and Zhou, Xiao-Dong and Wei, Shuya "Improved cycle performance of Li-CO2 batteries with nickel manganite supported carbon nanotube NiMn2O4 @CNT cathode" Journal of the Electrochemical Society , 2023 Citation Details
(Showing: 1 - 10 of 20)

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